Below is the powershell script sample on how to call NET USE command to create a shared folder on any remote server.

$netShareSettings+= @{  "Server"="TargetServer";
                         "Path"="E:\MyFolderToBeShared";
                         "ShareName" = "SharedFolder";
                          "UserAndPermission" = ("Domain\user1;FULL","Domain\User2;FULL");
                      }

foreach($netShareSetting in $netShareSettings)
  {

   $script =
     {

        $userParam = "";

        foreach($pm in $args[0].UserAndPermission)
        {
                $arr = $pm.Split(";");
                $userName = $arr[0];
                $perm = $arr[1];
                $userParam+= "/grant:`"{0}`,{1}`" " -f $userName, $perm
        }

        $command = "net share {0}=`"{1}`" {2}" -f $args[0].ShareName,$args[0].Path, $userParam
        $msg = " Executing Command: '{0}' on '{1}'" -f $command,$args[0].Server
        $msg = Invoke-Expression $command | Out-String
        $msg = "  Results: " + $msg.Trim();
        Write-Host $msg

     }

     Invoke-Command -ScriptBlock $script -ComputerName $netShareSetting.Server -ArgumentList $netShareSetting
  }